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==History== The earliest recorded metal employed by humans appears to be gold which can be found free or "native". Small amounts of natural gold have been found in Spanish caves used during the late Paleolithic period, c. 40,000 BC. Silver, copper, tin and meteoric iron can also be found native, allowing a limited amount of metalworking in early cultures. Egyptian weapons made from meteoric iron in about 3000 B.C. were highly prized as "Daggers from Heaven". However, by learning to get copper and tin by heating rocks and combining copper and tin to make an alloy called bronze, the technology of metallurgy began about 3500 B.C. with the Bronze Age. The extraction of iron from its ore into a workable metal is much more difficult. It appears to have been invented by the Hittites in about 1200 B.C., beginning the Iron Age. The secret of extracting and working iron was a key factor in the success of the Philistines. Historical developments in ferrous metallurgy can be found in a wide variety of past cultures and civilizations. This includes the ancient and medieval kingdoms and empires of the Middle East and Near East, ancient Egypt and Anatolia (Turkey), Carthage, the Greeks and Romans of ancient Europe, medieval Europe, ancient and medieval China, ancient and medieval India, ancient and medieval Japan, etc. Of interest to note is that many applications, practices, and devices associated or involved in metallurgy were possibly established in ancient China before Europeans mastered these crafts (such as the innovation of the blast furnace, cast iron, steel, hydraulic-powered trip hammers, etc.). However, modern research suggests that Roman technology was far more sophisticated than hitherto supposed, especially in mining methods, metal extraction and forging. They were for example expert in hydraulic mining methods well before the Chinese, or any other civilization of the time. A 16th century book by Georg Agricola called De re metallica describes the highly developed and complex processes of mining metal ores, metal extraction and metallurgy of the time. Agricola has been described as the "father of metallurgy"
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