Diamagnetism

Diamagnetism is the property of an object which causes it to create a magnetic field in opposition of an externally applied magnetic field, thus causing a repulsive effect. Specifically, an external magnetic field alters the orbital velocity of electrons around their nuclei, thus changing the magnetic dipole moment in the direction opposing the external field. Diamagnets are materials with a magnetic permeability less than μ0 (a relative permeability less than 1).

Consequently, diamagnetism is a form of magnetism that is only exhibited by a substance in the presence of an externally applied magnetic field. It is generally quite a weak effect in most materials, although superconductors exhibit a strong effect.

Diamagnetic materials cause lines of magnetic flux to curve away from the material, and superconductors can exclude them completely (except for a very thin layer at the surface).

Diamagnetism is a very general phenomenon, because all paired electrons, including the electrons of an atom, will always make a weak contribution to the material's response. However, for materials that show some other form of magnetism (such as ferromagnetism or paramagnetism), the diamagnetism is completely overpowered. Substances that mostly display diamagnetic behaviour are termed diamagnetic materials, or diamagnets. Materials that are said to be diamagnetic are those that are usually considered by non-physicists to be "non-magnetic", and include water, wood, most organic compounds such as petroleum and some plastics, and many metals including copper, particularly the heavy ones with many core electrons, such as mercury, gold and bismuth. The diamagnetism of various molecular fragments are called Pascal's constants.